炼油技术与工程 ›› 2022, Vol. 52 ›› Issue (1): 36-43.

• 机械设备 • 上一篇    下一篇

蓄热氧化反应器在石化VOCs废气处理中的应用

王海波,刘忠生,刘志禹,王晶,廖昌建,王新,孟凡飞   

  1. 中国石油化工股份有限公司大连石油化工研究院,辽宁省大连市 116045
  • 收稿日期:2021-10-14 出版日期:2022-01-15 发布日期:2022-01-18
  • 作者简介:王海波,正高级工程师,本科,主要研究方向为化工设备及流程优化。联系电话:0411-39699399,E-mail:wanghb.fshy@sinopec.com。
  • 基金资助:
    国家自然科学基金联合基金项目(U20B6004)

Application of regenerative thermal oxidizer technology in treatment of petrochemical VOCs gas

Wang Haibo, Liu Zhongsheng, Liu Zhiyu, Wang Jing, Liao Changjian, Wang Xin, Meng Fanfei   

  1. SINOPEC Dalian Research Institute of Petroleum and Petrochemicals, Dalian, Liaoning 116045
  • Received:2021-10-14 Online:2022-01-15 Published:2022-01-18

摘要: 针对石油化工生产过程复杂挥发性有机物(VOCs)废气治理,开发了高效蓄热氧化反应器技术,利用开发的蓄热氧化反应器组合前端吸收及冷凝等废气预处理及浓度调节技术,在石油化工企业罐区、装车以及含油污水池逸散废气、汽油氧化脱硫醇尾气等挥发性有机物废气处理上进行了工业化应用,考察了双床蓄热氧化反应器和三床蓄热氧化反应器废气处理工业化应用效果。结果表明:三床蓄热氧化反应器处理效果明显好于双床蓄热氧化反应器。针对石油化工企业复杂VOCs废气,采用开发的三床蓄热氧化反应器处理后,净化气中非甲烷总烃质量浓度小于10 mg/m3,硫化氢、有机硫化物以及苯、甲苯、二甲苯等污染物浓度均低于检出限,优于国内外最严排放标准要求,实现了VOCs近零排放。

关键词: 蓄热氧化反应器, 石油化工, VOCs, 废气处理, FD-RTO, FT-RTO, F-PV提升阀

Abstract: For the treatment of complex volatile organic compounds (VOCs) exhaust gas in the process of petrochemical production, a high-efficiency regenerative thermal oxidation reactor technology was developed. Combined with exhaust gases pre-treatment and concentration regulation technology such as absorption and condensation, the regenerative thermal oxidation reactor has been applied industrially in exhaust gas treatment for tank area, loading, oil greasy pool and gasoline oxidation decathiol process in petrochemical enterprises. The industrial application effect of exhaust gas treatment using two-bed thermal oxidation reactor and three-bed thermal oxidation reactor was investigated respectively. The industrial experiments show that the effect of the three-bed thermal oxidation reactor is much better than that of the two-bed thermal oxidation reactor. For the complex VOCs exhaust gas in petrochemical enterprises, after treated by the three-bed thermal oxidation reactor, the total hydrocarbon concentration in the purified gas is less than 10 mg/m3, the concentration of hydrogen sulfide, organic sulfide, benzene, toluene, xylene is lower than the detection limits, which is superior to the most stringent emission standards, and realizing near zero emission of VOCs.

Key words: regenerative thermal oxidizer, petrochemical, VOCs, waste gas treatment, FD-RTO, FT-RTO, F-PV poppet valve