某炼油厂氢气和轻烃综合回收工艺分析

炼油技术与工程 ›› 2022, Vol. 52 ›› Issue (9): 28-31.

某炼油厂氢气和轻烃综合回收工艺分析

王园园¹,郭忠森², 周仕鑫¹, 谢磊², 常林杉¹

1.盘锦浩业化工有限公司; 2.大连理工大学盘锦产业技术研究院浩业分院

收稿日期:2022-04-07 出版日期:2022-09-15 发布日期:2022-09-20
作者简介:王园园，工程师，硕士，主要研究方向为炼油过程节能降耗。联系电话：13125688729,E-mail:wyy13125688729@126.com。

Comperhensive recovery of hydrogen and light hydrocarbon in a refinery

Wang Yuanyuan¹,Guo Zhongsen²,Zhou Shixin¹,Xie Lei²,Chang Linshan¹

1.Panjin Haoye Chemical Co., Ltd.; 2.Panjin Institute of Industrial Technology, Dalian University of Technology

Received:2022-04-07 Online:2022-09-15 Published:2022-09-20

摘要/Abstract

摘要：

以提高炼油厂中氢气和轻烃的利用效率为目标，对炼油厂中氢气和轻烃的回收工艺进行了研究。对于炼厂气先进行氢气回收，根据氢浓度的不同，将膜分离与变压吸附分离技术耦合，氢气回收率可达93.26%,纯度(体积分数)可达98.7%。回收氢气后的炼厂气再进行轻烃回收。分别比较了低温冷凝、有机蒸汽膜分离和油吸收技术的回收效果和经济效益。结果表明：有机蒸汽膜分离技术轻烃回收率最高，为90.32%,经济效益最高可达6 286万元/a;油吸收技术回收轻烃经济效益最高，最优操作时达6 456万元/a,回收率为87.75%。实际应用中可根据厂区实际情况选择轻烃回收工艺。

关键词: 炼厂气, 氢气回收, 轻烃回收, 膜分离法, 低温冷凝法, 有机蒸汽膜法, 油吸收法, 经济效益

Abstract:

To improve the utilization efficiency of hydrogen and light hydrocarbon in refineries, the recoveryprocess of hydrogen and light hydrocarbon in refineries is studied. For hydrogen recovery from refinery gas, the membrane separation and pressure swing adsorption separation technology can be coupled according to the different concentration of hydrogen, the hydrogen recovery rate can reach 93.26%, the purity is 98.7%. Light hydrocarbon will be recovered from the refinery gas after recovering hydrogen. The recovery effects and economic benefits of low temperature condensation, organic vapor membrane separation and oil absorption technologies are compared. The results show that the light hydrocarbon recovery rate of organic vapor membrane separation technology is the highest, which is 90.32%, and the maximum economic benefit can reach 62.86 million yuan per year; The economic benefit of light hydrocarbon recovery by oil absorption technology is the highest, which is 64.56 million yuan per year under the optimal operation, and the recovery rate is 87.75%. In practical application, light hydrocarbon recovery process can be selected according to the actual situation of the refinery.

Key words: refinery gas, hydrogen recovery, light hydrocarbon recovery, membrane separation, low temperature condensation method, organic vapor membrane method, oil absorption method, economic benefit

王园园, 郭忠森, 周仕鑫, 谢磊, 常林杉. 某炼油厂氢气和轻烃综合回收工艺分析[J]. 炼油技术与工程, 2022, 52(9): 28-31.

Wang Yuanyuan, Guo Zhongsen, Zhou Shixin, Xie Lei, Chang Linshan . Comperhensive recovery of hydrogen and light hydrocarbon in a refinery[J]. Petroleum Refinery Engineering, 2022, 52(9): 28-31.

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