炼油技术与工程 ›› 2021, Vol. 51 ›› Issue (9): 28-31.

• 加工工艺 • 上一篇    下一篇

制氢转化炉低温SCR脱硝技术的应用

徐涛, 汪根宝, 范艺   

  1. 中石化南京工程有限公司,江苏省南京市 211100
  • 收稿日期:2021-04-29 发布日期:2021-11-12
  • 作者简介:徐涛,高级工程师,本科。联系电话:025-85936076,E-mail:xutao.snei@sinopec.com。

Application of SCR denitration technology at low temperature in hydrogen production reformer

Xu Tao, Wang Genbao, Fan Yi   

  1. SINOPEC Nanjing Engineering Co., Ltd., Nanjing, Jiangsu 211100
  • Received:2021-04-29 Published:2021-11-12

摘要: 目前应用在制氢转化炉上的成熟低温脱硝技术主要有低氮燃烧技术和选择性催化还原技术(SCR),低温SCR脱硝技术更适合石化制氢转化炉脱硝改造。脱硝技术关键在催化剂的选择。通过改造实例,提出采用国产锰系催化剂实施低温脱硝技术改造,使转化炉的出口NOx质量浓度稳定在50 mg/m3以下,具有维持制氢转化炉原有工艺流程配置、性能稳定、技术可靠、投资少的优点;在改造设计过程中,采用流场模拟、系统优化等辅助设计,可降低建设投资,提高运行可靠性;可以为制氢转化炉脱硝改造提供参考。

关键词: 制氢转化炉, 烟气脱硝, 低温SCR, 催化剂, 反应器

Abstract: At present, the mature low temperature denitration technologies applied in hydrogen production reformer mainly include low nitrogen combustion technology and selective catalytic reduction technology (SCR). Low temperature SCR denitration technology is more suitable for denitration transformation of petrochemical hydrogen production reformer. The key of denitration technology lies in the selection of catalyst. Through the transformation example, this paper puts forward the technical transformation of low temperature denitration with domestic manganese catalyst to stabilize the NOx concentration at the outlet of reformer below 50 mg/m3, which has the characteristics of maintaining the original process flow configuration of hydrogen production reformer, stable performance, reliable technology and low investment. In the process of reconstruction design, auxiliary design such as flow field simulation and system optimization can reduce construction investment and improve operation reliability. It can provide reference for denitration transformation of hydrogen production reformer.    

Key words: hydrogen production reformer, flue gas denitration, low temperature SCR, catalyst, reactor