炼油技术与工程 ›› 2024, Vol. 54 ›› Issue (10): 16-19.

• 加工工艺 • 上一篇    下一篇

固定床渣油加氢技术及渣油高效转化技术应用

邵志才   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2024-03-22 出版日期:2024-10-15 发布日期:2024-10-22
  • 作者简介:邵志才,研究员,主要从事加氢工艺的研究工作。

Application of fixed-bed residue hydrotreating technology and residue high efficiency conversion technology

Shao Zhicai   

  1. SINOPEC Research Institute of Petroleum Processing Co., Ltd.
  • Received:2024-03-22 Online:2024-10-15 Published:2024-10-22

摘要: 固定床渣油加氢技术一般不加工100%减渣油,其装置混合原料中减渣油质量分数一般不高于65%。A固定床渣油加氢装置6个周期运行结果表明:原料中减渣油比例越高,装置运行周期越短。B固定床渣油加氢装置体积空速为0.20 h−1,若体积空速降低至0.15、0.10 h−1,反应器压力降预计分别增加至2.3、3.4 MPa。A固定床渣油加氢装置加氢重油产率高达93.25%,520℃以上馏分转化率仅为25.38%。沸腾床渣油加氢技术及浆态床渣油加氢技术可以加工100%减渣油。C沸腾床渣油加氢装置和D浆态床渣油加氢装置反应器压力降稳定,其中D装置反应器压力降仅为0.42 MPa。典型沸腾床渣油加氢技术和浆态床渣油加氢技术的转化率可达85.87%和91.49%。

关键词: font-family:-apple-system, blinkmacsystemfont, ", font-size:14px, background-color:#FFFFFF, ">固定床渣油加氢, 高效转化, 减渣油, 体积空速, 转化率, 反应系统压力降, 渣油加氢裂化

Abstract: Generally, 100% vacuum residue is not processed in fixed-bed residue hydrotreating units, and the proportion of vacuum residue in the feedstock is not higher than 65%. The operating results of the A fixed-bed residue hydrotreating unit over six cycles show that the higher the proportion of vacuum residue in the feedstock, the shorter the operating cycle of the unit. The volume space velocity of the B fixed-bed residue hydrotreating unit is 0.20 h−1. If the volume space velocity is reduced to 0.15 h−1 and 0.10 h−1, the reactor pressure drop is expected to increase to 2.3 MPa and 3.4 MPa, respectively. The yield of hydrogenated heavy oil in the A fixed-bed residue hydrotreating unit is as high as 93.25%, and the conversion rate of fractions above 520℃ is only 25.38%. Ebullated bed residue hydrocracking technology and slurry bed residue hydrocracking technology can process 100% vacuum residue. The pressure drop in the reactors of the C ebullated bed residue hydrocracking unit and the D slurry bed residue hydrocracking unit is stable, with a pressure drop of only 0.42 MPa in the reactor of unit D. The conversion rates of typical ebullated bed residue hydrocracking technology and slurry bed residue hydrocracking technology can reach 85.87% and 91.49%, respectively.

Key words: font-family:-apple-system, blinkmacsystemfont, ", font-size:14px, background-color:#FFFFFF, ">fixed bed residue hydrotreating, efficient conversion, vacuum residue, volume space velocity, conversion rate, reaction system pressure drop, residue hydrocracking