炼油技术与工程 ›› 2025, Vol. 55 ›› Issue (3): 22-25.

• 催化剂和助剂 • 上一篇    下一篇

柴油加氢裂化装置全体相金属催化剂应用总结

童军,黎臣麟,武宝平,郭晓雷,陈马奔,周杰   

  1. 中国石油四川石化有限责任公司
  • 收稿日期:2024-10-01 出版日期:2025-03-15 发布日期:2025-03-21
  • 作者简介:童军,高级工程师,2005年毕业于长江大学化学工程与工艺专业,主要从事加氢裂化装置生产技术管理工作。E-mail:495714535@qq.com

Summary of the application of all-phase metal catalyst in diesel hydrocracking unit

Tong Jun, Li Chenlin, Wu Baoping, Guo Xiaolei, Chen Maben, Zhou Jie   

  1. PetroChina Sichuan Petrochemical Co., Ltd.
  • Received:2024-10-01 Online:2025-03-15 Published:2025-03-21

摘要:

为了提高柴油产品质量,降低柴油收率,某公司将3.5 Mt/a柴油加氢精制装置改造为3.0 Mt/a柴油加氢裂化装置。采用全体相金属催化剂Nebula 20实现中压柴油加氢装置在单台反应器高空速工况下生产国Ⅵ柴油,增产部分重石脑油。在精制体积空速2.08 h⁻¹,裂化体积空速4.39 h⁻¹情况下,柴油收率为81%,达到了降低柴油收率的目的。控制原料中二次油占比不高于20%,原料95%点回收温度不高于363℃,原料氮质量分数不高于397 μg/g的情况下,精制催化剂失活速率0.42℃/月,裂化催化剂失活速率0.33℃/月,催化剂连续运行62个月。表明采用高活性催化剂级配技术能够实现柴油质量升级,同时延长催化剂的使用寿命。

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Abstract:

In order to improve the quality of diesel products and reduce the diesel yield, a 3.5 Mt/a diesel hydrotreating unit was transformed into a 3.0 Mt/a diesel hydrocracking unit. The all-phase metal catalyst Nebula 20 was adopted to achieve the production of Guo VI diesel and partially increase the production of heavy naphtha under the condition of high volumetric space velocity in a single reactor. Under the conditions of hydrotreating volumetric space velocity of 2.08 h⁻¹ and hydrocracking volumetric space velocity of 4.39 h⁻¹, the diesel yield was 81%, achieving the goal of reducing the diesel yield. Under the conditions of controlling the proportion of secondary oil processing in the feedstock to not exceed 20%, the 95% point temperature of the feedstock to not exceed 363℃, and the nitrogen content of the feedstock to not exceed 397 μg/g, the deactivation rate of the hydrotreating catalyst was 0.42℃/month, and the deactivation rate of the hydrocracking catalyst was 0.33℃/month, with the catalyst running continuously for 62 months. It indicates that the high-activity catalyst grading technology can achieve the upgrading of diesel quality and extend the service life of the catalyst.

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