炼油技术与工程 ›› 2024, Vol. 54 ›› Issue (8): 18-23.

• 加工工艺 • 上一篇    下一篇

沸腾床渣油加氢装置运行及优化

李 想   

  1. 中国石油化工股份有限公司镇海炼化分公司
  • 出版日期:2024-08-15 发布日期:2024-09-13
  • 作者简介:李想,工程师,大学本科,毕业于西南石油大学高分子材料与工程专业,现从事炼油化工发展规划及技术管理工作。联系电话:152578815567,E-mail: lix00.zhlh@sinopec.com。

Operation and optimization of fluidized bed residue hydrogenation unit

Li Xiang

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  1. SINOPEC Zhenhai Refining & Chemical Company
  • Online:2024-08-15 Published:2024-09-13

摘要: 文中结合工业运行数据,研究了影响沸腾床渣油加氢装置长周期稳定运行的因素,并提出优化措施。结果表明,反应沉淀和杂质脱除率对沸腾床渣油加氢装置长周期稳定运行有较大影响。可以通过降低转化率和/或减小渣油流量来减少反应沉淀,转化率降低1个百分点,反应沉淀物指数减小0.03个百分点;也可以通过增加原料中稠环芳烃的比例抑制沥青质析出,进而减少反应沉淀,稠环芳烃掺炼比例多5个百分点,反应沉淀物指数降低0.02个百分点。减小催化剂金属沉积率会使杂质脱除率增加,可采用增加催化剂加排量的方式减小催化剂金属沉积率,达到增加杂质脱除率的目的。提高反应温度会使杂质脱除率增加,但同时也会使反应沉淀增加。

关键词: font-family:-apple-system, blinkmacsystemfont, ", font-size:14px, background-color:#FFFFFF, ">沸腾床, 渣油加氢装置, 反应沉淀, 转化率, 混合渣油性质, 杂质脱除率, 催化剂加排量, 反应温度

Abstract: Based on industrial operation data, the factors affecting the long-term stable operation of a fluidized bed residue hydrogenation unit were studied, and optimization measures were proposed. The results indicate that reaction precipitation and impurity removal rate have a significant impact on the long-term stable operation of the fluidized bed residue hydrogenation unit; reaction sediment can be reduced by lowering the conversion rate and/or reducing the residue oil flow rate, with a 1 percentage point decrease in conversion rate leading to a 0.03 percentage point decrease in the reaction sediment index; it is also possible to suppress the precipitation of asphaltenes by increasing the proportion of polycyclic aromatic hydrocarbons in the feedstock, thereby reducing reaction precipitation, with a 5 percentage point increase in the blending ratio of polycyclic aromatic hydrocarbons leading to a 0.02 percentage point decrease in the reaction sediment index. Reducing the metal deposition rate of the catalyst will increase the impurity removal rate, and the metal deposition rate of the catalyst can be reduced by increasing the catalyst addition and discharge amount to achieve the goal of increasing the impurity removal rate. Raising the reaction temperature will increase the impurity removal rate, but it will also increase the reaction precipitation.

Key words: font-family:-apple-system, blinkmacsystemfont, ", font-size:14px, background-color:#FFFFFF, ">fluidized bed, residue hydrogenation unit, reaction precipitation, conversion rate, properties of mixed residue oil, impurity removal rate, catalyst addition amount, reaction temperature