Research progress in improving the DCC performance of ZSM-5 molecular sieve

Petroleum Refinery Engineering ›› 2025, Vol. 55 ›› Issue (7): 44-47.

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Research progress in improving the DCC performance of ZSM-5 molecular sieve

Yang Qi, Duan Hongchang, Ma Junfu, Peng Wei, Song Wenqiang, Lv Penggang, Wang Xinyu, Guo Rong

1.Lanzhou Petrochemical Research Center, Petrochemical Research Institute, PetroChina, Lanzhou, Gansu 730000； 2.China University of Petroleum-Beijing at Karamay, Karamay, Xinjiang 834000； 3.PetroChina Qinghai Oilfield Golmud Refinery, Golmud, Qinghai 816099； 4.Xi’an Shiyou University, Xi’an, Shaanxi 710065

Online:2025-07-15 Published:2025-07-21

提高ZSM-5分子筛催化裂解性能研究进展

杨琦, 段宏昌, 马俊福, 彭威, 宋文强, 吕鹏刚, 王新宇, 郭蓉

1.中国石油石油化工研究院兰州化工研究中心, 甘肃省兰州市730000； 2.中国石油大学(北京)克拉玛依校区, 新疆克拉玛依834000； 3.中国石油青海油田格尔木炼油厂, 青海省格尔木市816099； 4.西安石油大学, 陕西省西安市710065

作者简介:杨琦, 硕士, 主要研究方向为催化裂化技术。
基金资助:
中国石油基础性前瞻性专项（2023ZZ36）

Abstract

Abstract:

This paper reviews various methods to improve the deep catalytic cracking (DCC) performance of ZSM-5 molecular sieve, including the synthesis of nano-molecular sieve, the introduction of mesoporous or hierarchical pore structures, and the modulation of acidity. Nanoscale ZSM-5 molecular sieve contributes to the improvement of light olefin selectivity due to its small grain size and large specific surface area, the introduction of mesoporous structure improves the diffusion rate of macromolecules within the pores, and elemental doping to modulate the acidity can further optimize olefin selectivity and product distribution. In addition, the future research direction of ZSM-5 molecular sieve performance optimization is envisioned, which combines advanced simulation calculation and characterization techniques to achieve more precise catalytic regulation through an in-depth understanding of its structure-activity relationship and catalytic mechanism.

Key words: ZSM-5 molecular sieve, DCC performance, hierarchical pore structure, metallic modification, non-metallic modification, acidic sites, aluminum distribution modulation

摘要：

综述了提高ZSM-5分子筛催化裂解性能的多种方法，包括合成纳米级分子筛、引入介孔或多级孔结构以及调节酸性等。纳米级ZSM-5分子筛因其小晶粒和大比表面积，有助于提高轻质烯烃选择性；引入介孔结构改善了大分子在孔道内的扩散速率；引入金属或非金属元素调节酸性，能够进一步优化烯烃选择性和产品分布。此外，展望了未来ZSM-5分子筛性能优化的研究方向，结合先进的模拟计算与表征技术，通过深入理解其构效关系和催化机理，实现更精准的催化裂解性能调控。

关键词: ZSM-5分子筛, 催化裂解性能, 多级孔结构, 金属改性, 非金属改性, 酸性位点, 铝落位调控

Yang Qi, Duan Hongchang, Ma Junfu, Peng Wei, Song Wenqiang, Lv Penggang, Wang Xinyu, Guo Rong. Research progress in improving the DCC performance of ZSM-5 molecular sieve[J]. Petroleum Refinery Engineering, 2025, 55(7): 44-47.

杨琦, 段宏昌, 马俊福, 彭威, 宋文强, 吕鹏刚, 王新宇, 郭蓉. 提高ZSM-5分子筛催化裂解性能研究进展[J]. 炼油技术与工程, 2025, 55(7): 44-47.

References

[1] Wang P, Xiao X, Pan Y, et al. Facile synthesis of nanosheet-stacked hierarchical ZSM-5 zeolite for efficient catalytic cracking of n-octane to produce light olefins[J]. Catalysts, 2022, 12(3): 351.

[2] 张淑莹, 陶金泉, 沈杨, 等. 纳米薄层ZSM-5分子筛的低成本合成及其催化裂解性能[J]. 石油化工, 2022, 51(9): 1017-1025.

[3] Hao J, Xu S M, Cheng D G, et al. Synthesis of nanosheet epitaxial growth ZSM-5 zeolite with increased diffusivity and its catalytic cracking performance[J]. Catalysis Science & Technology, 2022, 12(12): 3912-3920.

[4] Zhu J, Yan S, Qian Y, et al. Fabrication of fluffy-ball like ZSM-5 zeolite and its application in hexane catalytic cracking[J]. Microporous and Mesoporous Materials, 2023, 351: 112465.

[5] Ghazimoradi M Soltanali S, Safari N, et al. Synthesis of fluorinated ZSM-5 catalysts fluoride effect on structure properties and coke resistance in n-hexane catalytic cracking[J]. Journal of Materials Science, 2023, 58(28): 11551-11567.

[6] 郑云峰, 樊红超, 汪毅, 等. ZSM-5分子筛介孔化及其在多产低碳烯烃中的应用[J]. 石化技术与应用, 2022, 40(4): 243-246.

[7] Talebian-Kiakalaieh A, Tariqhi S. Synthesis of hierarchical Y and ZSM-5 zeolites using post-treatment approach to maximize catalytic cracking performance[J]. Journal of Industrial and Engineering Chemistry, 2020, 88: 167-177.

[8] Zhang X, Cheng D G, Chen F, et al. n-Heptane catalytic cracking on hierarchical ZSM-5 zeolite the effect of mesopores[J]. Chemical Engineering Science, 2017, 168: 352-359.

[9] Liu S, Tian Y, He X, et al. Moderation of textural properties in hierarchical ZSM-5 to enhance the yield of olefins in catalytic cracking of hydrocarbons[J]. Catalysis Science & Technology, 2023, 13(4): 1119-1127.

[10] Hartanto D, Kurniawati R, Pambudi A B, et al. One-pot non-template synthesis of hierarchical ZSM-5 from kaolin source[J]. Solid State Sciences, 2019, 87: 150-154.

[11] Wu L, Su H, Sun X, et al. Catalytic cracking for propylene production over Au catalyst supported by external surface-modified ZSM-5 zeolite[J]. Catalysts, 2022, 12(4): 418.

[12] 崔孟涛, 王忠, 李学兵, 等. 含骨架铁ZSM-5的合成及其负载Pt催化剂在正十二烷脱氢反应中的催化性能[J]. 无机化学学报, 2020, 36(5): 885-892.

[13] 李琦, 张强, 赵慧莹, 等. 纳米片Ga-MFI分子筛合成及其对航空燃油催化裂解反应中低碳烯烃选择性的影响[J]. 化工进展, 2019, 38(9): 4075-4084.

[14] 张剑秋. 污染金属对FCC工业平衡剂性质的影响[J]. 炼油技术与工程, 2013, 43(3): 45-50.

[15] 赵鸣芝, 段宏昌, 吕鹏刚, 等. 密度泛函理论计算ZSM-5分子筛酸性的研究进展[J]. 石化技术与应用, 2024, 42(4): 314-318.

Research progress in improving the DCC performance of ZSM-5 molecular sieve

提高ZSM-5分子筛催化裂解性能研究进展

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