炼油技术与工程 ›› 2023, Vol. 53 ›› Issue (10): 12-16.

• 加工工艺 • 上一篇    下一篇

烃类蒸汽转化制氢装置高温变换和中温变换方案对比

司马蒙   

  1. 中石化广州工程有限公司
  • 收稿日期:2023-07-03 出版日期:2023-10-15 发布日期:2023-10-19
  • 作者简介:司马蒙,工程师,硕士研究生,2014年毕业于中国石油大学(北京)化学工程专业,长期从事炼油工艺设计工作。联系电话:020-22192873,E-mail:simam.lpec@sinopec.com。;

Comparison of schemes of high temperature shift and medium temperature shift of hydrocarbon steam reforming for hydrogen production unit

Sima Meng   

  1. SINOPEC Guangzhou Engineering Co., Ltd.
  • Received:2023-07-03 Online:2023-10-15 Published:2023-10-19

摘要:

以某炼油厂原料气为研究对象,设计了两种方案,在工程投资、能耗、操作费用等方面进行了对比。其中,方案一为蒸汽转化+高温变换流程,方案二为蒸汽转化+中温变换流程。结果表明:在项目用地面积充裕、工程投资充足、项目蒸汽紧缺的情况下,方案二的CO转化率高、原料消耗量低、外输蒸汽量多、能耗低、操作费用低,此时方案二更有优势;在项目用地面积紧张、工程投资有限、项目蒸汽富裕的情况下,方案二需要考虑独立的中温变换开工还原流程及设备,开工流程复杂,催化剂费用高,占地面积相应增加,而方案一的工程投资低、占地面积小,此时方案一更有优势。

关键词: 烃类蒸汽转化, 制氢装置, 高温变换, 中温变换, 开工还原, 工程投资, 能耗, 操作费用

Abstract:

Two schemes are designed based on the raw gas of a certain refinery, and comparisons are made in terms of engineering investment, energy consumption, and operating costs. Scheme 1 is steam reforming + high temperature shift, while Scheme 2 is steam reforming + medium temperature shift. The results show that in the case of abundant land area, sufficient engineering investment, and shortage of project steam, Scheme 2 has higher CO conversion rate, lower raw material consumption, more steam output, lower energy consumption, and lower operating costs. At this time, Scheme 2 has more advantages. In the case of tight project land area, limited engineering investment, and abundant project steam, Scheme 2 needs to consider an independent medium temperature shift start-up reduction process and equipment. The start-up process is complex, the catalyst cost is high, and the land occupation area increases accordingly. However, Scheme 1 has lower engineering investment and small land occupation area, which makes Scheme 1 more advantageous.

Key words: hydrocarbon steam reforming, hydrogen production unit, high temperature shift, medium temperature shift, start-up reduction, project investment, energy consumption, operating cost