Petroleum Refinery Engineering ›› 2024, Vol. 54 ›› Issue (9): 13-16.

• PROCESSING • Previous Articles     Next Articles

Progress in zeolite molecular sieve-based inorganic membrane pervaporation and gas separation technologies

Yu Ji, Han Xinhong, Xu Wanyi, Liao Changjian   

  1. SINOPEC (Dalian) Petrochemical Research Institute Co., Ltd.
  • Online:2024-09-15 Published:2024-09-27

基于沸石分子筛的无机膜渗透蒸发和气体分离技术进展

余 稷,韩昕宏,徐婉怡,廖昌建   

  1. 中石化(大连)石油化工研究院有限公司
  • 作者简介:余 稷,助理研究员,硕士研究生,2015年毕业与中国石油大学(北京)化学工程与技术专业,主要研究方向为环境保护。联系电话:1580411245,E-mail: yuji.fshy@sinopec.com
  • 基金资助:
    国家重点研发计划(2023YFB3810704)

Abstract: Compared with traditional separation technologies, membrane separation technology has the advantages of high separation efficiency, low energy consumption, and is easy to integrate with other technologies. Compared with organic separation membranes, inorganic membranes have the advantages of high stability, large mechanical strength, high separation efficiency, and resistance to microbial erosion. This paper introduces the types of commonly used molecular sieve membranes, discusses the main preparation methods of molecular sieve membranes, and elaborates on the application progress of molecular sieve membranes in the fields of pervaporation and gas separation, such as hydrogen recovery, natural gas purification, carbon dioxide capture, and hydrocarbon mixture separation. The existing problems are analyzed, and the future development is prospected, emphasizing the research focus on reducing manufacturing costs, improving the preparation technology of molecular sieve membranes, and meeting the challenges of multi-component separation.

Key words: font-family:-apple-system, blinkmacsystemfont, ", font-size:14px, background-color:#FFFFFF, ">zeolite molecular sieve, inorganic membrane, gas separation, pervaporation, hydrogen recovery, natural gas purification, carbon dioxide capture, hydrocarbon mixture separation

摘要: 相比于传统分离技术,膜分离技术具有分离效率高、能耗低、便于与其他技术集成等优点。与有机分离膜相比,无机膜具有稳定性高、机械强度大、分离效率高、耐微生物侵蚀等优势。针对基于沸石分子筛的无机膜分离技术,介绍了当前常用分子筛膜的种类;探讨了分子筛膜的主要制备方法;详细阐述了分子筛膜在渗透蒸发以及气体分离领域中的应用进展,如氢气回收、天然气净化、二氧化碳捕集和烃混合物分离。对当前存在的问题进行了分析并对今后的发展进行了展望,强调了在降低制造成本、提升分子筛膜制备技术、应对多组分分离挑战等方面的研究重点。

关键词: font-family:-apple-system, blinkmacsystemfont, ", font-size:14px, background-color:#FFFFFF, ">沸石分子筛, 无机膜, 气体分离, 渗透蒸发, 氢气回收, 天然气净化, 二氧化碳捕集, 烃混合物分离